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You are here: Home / Fluoride Crystal / NaF

NaF

Sodium fluoride (NaF) is an inorganic salt, which is an important source of the fluoride ion for many applications. Sodium fluoride single crystal has a good transmission for more than 50% from 130nm to 13um.And the refractive index is very low. It is a simple ionic compound, made of the sodium (Na+) cation and fluoride (F-) anion. The solid salt exists as cubic crystals similar to the crystal structure of sodium chloride (NaCl). Sodium fluoride occurs in nature as the rare mineral villiaumite, in very small quantities. Sodium fluoride is widely used as a fluorinating agent in toothpastes and water supplies to maintain dental health. It is also used as a wood preservative, corrosion inhibitor, cleaning agent, insecticide, chemical reagent, and in metallurgy and glass industries. Another important application is in nuclear medical imaging, where radioactive sodium fluoride (NaF18) is used as a radiotracer for detecting various conditions. As a kind of alkali halide crystal, sodium fluoride single crystal has a wide range of optical tansmission, but it has not been paid much attention because it is inferior to other crystals (such as calcium fluoride, magnesium fluoride, etc.) in mechanical properties and corrosion resistance In recent years, with the continuous progress in the application of color centers in crystal materials, sodium fluoride crystal has become a remarkable crystal material.

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Parameter

Physical and Chemical Properties
Crystal StructureSingle crystal, synthetic
Crystal TypeCubic, NaCl type
Lattice Constants4.62
Cleavage Planes-100
Density2.79 g/cm3
Melting Point996°C
Solubility in Water(g/100g)4.13
Thermal Conductivity /(W·m-1·K-1@250K)22
Specific Heat/ (J·kg-1·K-1)1088
Thermal Expansion /(10-6·K-1@298K )36
Hardness (Mohs)60
Young`s Modulus /GPa76
Shear Modulus/GPa30.7
Bulk Modulus/GPa48.5
Elastic Coefficient/GPaC11 = 97; C12 = 24.2; C44 = 28.1
Optical Characteristics
Transmission Range(50%)0.13 … 13 µm @thickness 1mm 
Refractive Index  1.324535 @0.633 µm  
Reflective Loss 1.15% @10 µm 
Poisson Ratio0.24
Dielectric Constant@292K6.0@2MHz
Reststrahlen34µm
Spectrum

Feature
Application
Literature
Feature
  • Transmission from 120nm to 7um
  • Very low refractive index
  • Unsoluble in ethanol
  • Must be kept away from oxidizing agents, metals, acids, alkalis
  • Less hygroscopic
Application
  • Cherenkov-counter, AR coating material
  • Optical glass grade coating materials
  • Medication like teeth
  • Color center laser substrate material
  • Ionizing radiation dose display material
Literature

[1] E.F. El Agammy, H. Doweidar, K. El-Egili,等. Structure of NaF–TeO2 glasses and glass-ceramics[J]. Ceramics International, 2020.
[2] Zhang X , Liu X , He M , et al. A molecular dynamics simulation study of KF and NaF ion pairs in hydrothermal fluids[J]. Fluid Phase Equilibria, 2020, 518:112625.
[3] Gdra B , Acjr A , Jagc D , et al. Efficient extraction of lithium from β-spodumene by direct roasting with NaF and leaching[J]. Chemical Engineering Research and Design, 2019, 150:320-326.
[4] Guo H , Li J , Zhang H , et al. Study on micro-structure and transport properties of KF-NaF-AlF3-Al2O3 system by first-principles molecular dynamics simulation[J]. Journal of Fluorine Chemistry, 2020, 235:109546.
[5] Dirciane, Perpétuo, Reis, et al. Remineralizing potential of dental composites containing silanized silica-hydroxyapatite (Si-HAp) nanoporous particles charged with sodium fluoride (NaF).[J]. Journal of dentistry, 2019, 90:103211-103211.
[6] Botman E , Raijmakers P , Yaqub M , et al. Evolution of heterotopic bone in fibrodysplasia ossificans progressiva: An [ 18 F]NaF PET/CT study[J]. Bone, 2019.
[7] Li W , Jing W , Mei B , et al. Effect of NaF doping on the transparency, microstructure and spectral properties of Yb3+: CaF2 transparent ceramics[J]. Journal of the European Ceramic Society, 2020, 40(13).
[8] Yeung S , Toor A , Deib G , et al. Relationship between lower lumbar spine shape and patient bone metabolic activity as characterised by 18F NaF bio-markers[J]. Computers in Biology and Medicine, 2019, 116:103529.
[9] Yin H , Wu S , X Wang, et al. Thermodynamic description for the NaF-KF-RbF-ZnF2 system[J]. Journal of Fluorine Chemistry, 2018, 217.
[10] Keshri S R , Bodewad V V , Jagtap A A , et al. Influence of NaF on the ionic conductivity of sodium aluminophosphate glass electrolytes[J]. Materials Letters, 2020, 271:127763.
[11] Ming L , Xxa B , Ql B , et al. Direct electrolytic separation of tungsten and cobalt from waste cemented carbide and electrochemical behavior of tungsten and cobalt ions in NaF–KF molten salts[J]. Journal of Electroanalytical Chemistry, 2019, 833:480-489.
[12] Wang Y , Ling C , Yin H , et al. Thermophysical properties of KCl-NaF reciprocal eutectic by artificial neural network prediction and experimental measurements[J]. Solar Energy, 2020, 204:667-672.
[13] Guo H , Li J , Zhang H , et al. First-principles molecular dynamics investigation on KF-NaF-AlF3 molten salt system[J]. Chemical Physics Letters, 2019, 730:587-593.
[14] Zhang J , Yang X , Yu S , et al. Roughening of hollow glass microspheres by NaF for Ni electroless plating[J]. Surface and Coatings Technology, 2018.
[15] Sms A , Kk B , Kp B , et al. Evaluation of the diagnostic performance of 18 F-NaF positron emission tomography/computed tomography in patients with suspected ankylosing spondylitis according to the Assessment of SpondyloArthritis International Society criteria[J]. The Spine Journal, 2020, 20( 9):1471-1479.
[16] Mj A , Sbm A , Enn A , et al. Synergistic effects of sodium fluoride (NaF) on the crystallinity and band gap of Fe-doped TiO 2 developed via microwave-assisted hydrothermal treatment[J]. Optical Materials, 104.
[17] Yin H , Zhang P , An X , et al. Thermodynamic modeling of LiF-NaF-KF-CrF 3 system[J]. Journal of Fluorine Chemistry, 2018, 209:6-13.
[18] Lv X , Han Z , Chen J , et al. First-principles molecular dynamics study of ionic structure and transport properties of LiF-NaF-AlF 3 molten salt[J]. Chemical Physics Letters, 2018, 706:237-242.
[19] JA Ocádiz-Flores, E Carré, Griveau J C , et al. Thermodynamic assessment of the KF-ThF4, LiF-KF-ThF4 and NaF-KF-ThF4 systems[J]. The Journal of Chemical Thermodynamics, 2020, 145:106069.
[20] Chandrasekaran S , Gerdts C , Robinson Y , et al. Safety and effectiveness of one-day later abortion procedures: A retrospective chart review[J]. Contraception, 2020, 101(5):356.
[21] Qiu Z , Li Z , Fu H , et al. Corrosion mechanisms of Zr-based bulk metallic glass in NaF and NaCl solutions[J]. Journal of Materials Science and Technology -Shenyang-, 2020, 46:33-43.
[22] Eekhoff E , Botman E , Netelenbos J C , et al. [18F]NaF PET/CT scan as an early marker of heterotopic ossification in fibrodysplasia ossificans progressiva[J]. Bone, 2017:143.
[23] Effect of NaF pre-cursor on alumina and hafnia rear contact passivation layers in ultra-thin Cu(In,Ga)Se2 solar cells[J]. Thin Solid Films, 2019, 683.
[24] Neina V , Pabst W . Highly dense spinel ceramics with completely suppressed grain growth prepared via SPS with NaF as a sintering additive[J]. Journal of the European Ceramic Society, 2020.
[25] Wang Y , J Ge, Zhuo W , et al. Electrochemical extraction of lanthanum in molten fluoride salts assisted by KF or NaF[J]. Electrochemistry Communications, 2019, 104.
[26] Victor, Mosquim, Larissa, et al. Can TiF4 varnish or TiF4/NaF solution stain eroded and sound enamel?[J]. Journal of dentistry, 2019.
[27] Mukherjee S , Dash S . Thermodynamic study of NaLaF4 in NaF-LaF3 system using solid state electrochemical cell method[J]. Journal of Solid State Chemistry, 2019, 277:61-67.
[28] Dwivedi A K , Kumar M , Mishra G , et al. Optimization of controlling parameters of plasma torch aerosol generator and characteristics of synthesized metal oxide aerosols in context of NAF program[J]. Progress in Nuclear Energy, 2020, 123:103311.
[29] Widenheim J , Birkhed D , Hase J C , et al. Effect on approximal caries in teenagers of interrupting a school‐based weekly NaF mouthrinse program for 3 years[J]. Community Dentistry and Oral Epidemiology, 1989, 17(2).
[30] Wang X , Qi G . Separation and recovery of NaF from fluorine containing solution by the common ion effect of Na+[J]. Heliyon, 2018, 4(12):e01029.
[31] Kovacs R , Van P . Second sound and ballistic heat conduction: NaF experiments revisited[J]. International Journal of Heat & Mass Transfer, 2018, 117(feb.):682-690.

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